Lesson Structure Angular Momentum Ordinary angular momentum Generalized angular momentum Eigen function for angular momentum Eigen values of angular momentum Operator using ladder operators Addition of angular momentum Spin anti-symmetry Pauli exclusion principle Electronic Structure of Atoms Electronic configuration Russell-Saunders terms and coupling schemes Stater-Condon Parameters Term Separation Energies of the pn configuration Term Separation [...]
Lesson Structure 1Â Â Â Â Â Â Â Introduction 2Â Â Â Â Â Â Â Microstates, macrostates, ensembles 3Â Â Â Â Â Â Â Mathematical basics: probability theory 4Â Â Â Â Â Â Â The microcanonical ensemble 5Â Â Â Â Â Â Â The Boltzmann entropy and Boltzmann distribution 6Â Â Â Â Â Â Â The canonical ensemble 7Â Â Â Â Â Â Â Thermodynamic state functions 8Â Â Â Â Â Â Â Crystals 9Â Â Â Â Â Â Â Fermi-Dirac, Bose-Einstein, and Maxwell-Boltzmann statistics 10Â Â Â Â Â Ideal mono-atomic gas 11Â Â Â Â Â Ideal gas with internal degrees of freedom 12Â Â Â Â Â Mixtures of [...]
Aim: Estimation of phenol compound by brominating method. Required: 0.1 N Na2S2O3.5H2O solution, 0.1 N Brominating solution, 10% KI solution, con. HCl Procedure: Take 25 ml of given Phenol solution and dilute it up to 250 mL using distilled water in 250 mL conical flask take 10 mL of diluted solution in a stoppered bottle [...]
Aim: Estimation of Aniline compound by brominating method. Required: 0.1 N Na2S2O3.5H2O solution, 0.1 N Brominating solution, 10% KI solution, con. HCl Procedure: Take 25 ml of given Aniline solution and dilute it up to 250 mL using distilled water in 250 mL conical flask take 10 mL of diluted solution in a stoppered bottle [...]
Lesson Structure 1.0      Objectives 1.1      Introductions 1.2      Mechanism of free radical substitution 1.2.1   Free-radical substitution of alkanes 1.2.2   Free-radical halogenation is most commonly applied to allylic or benzylic halogenations      1.3      Neighbouring group assistance in free radical reactions 1.4      Reactivity 1.4.1   Reactivity for aliphatic substrates: 1.4.2   Reactivity in aromatic substrate: 1.4.3   Reactivity in the attacking radicals: [...]
Lesson Structure 1.0      Objectives 1.1      Introductions 1.1.1   Leaving groups as (or leaving) nucleophiles or nucleofuge 1.1.2   Incoming nucleophile  1.2.     Mechanism SN2 Reaction 1.3.     The SN1 mechanism (carbocation process) 1.3.1   Evidence for the SN1 mechanism 1.4.     Mixed SN1 and SN2 mechanism 1.5.     SNi mechanism 1.6.     SET mechanism 1.6.1   Evidence for SET mechanism: 1.7.     Neighbouring Group Participation [...]
Lesson Structure Conformational analysis of cycloalkanes Decalins Effect of Conformation on reactivity Conformation of sugars Steric strain due to unavoidable crowding Element of symmetry Chirality Molecules more than one chiral center threo and erythro isomers Method of resolution Optical purity Enantiotopic and diastereotopic atoms, groups and Faces Stereospecific and stereoselective synthesis Asymmetric synthesis Optical activity [...]
Aim: Determination the percentage purity of the given sample of a sulpha drug having molecular weight _________. Requirement: Acetone 10 % sodium acetate Potassium dichromate solution (10%) Standard AgNO3 Process: Weigh exactly about 0.2 gm of the given sample of sulpha drug and dissolve in a mixture of 25 ml Acetone & 20 ml 10 [...]
Aim: Determination the potency of the Penicillin G in per mg Requirement: 0.01N NaS2O3 solution 0.01N I2 solution 1 N NaOH solution (Approx.) 1 N HCl solution (Approx.) Process: Weigh exactly about 0.05 gm (50 mg) of the given penicillin and dissolve it in distilled water and finally make the volume 100 ml in Standard [...]
