The objective of this book is to make the concepts and methods of physical chemistry clear and interesting to students who have had a year of calculus and a year of physics. The underlying theory of chemical phenomena is complicated, and so it is a challenge to make the most important concepts and methods understandable to undergraduate students.

However, these basic ideas are accessible to students, and they will find them useful whether they are chemistry majors, biologists, engineers, or earth scientists. The basic theory of chemistry is presented from the viewpoint of academic physical chemists, but many applications of physical chemistry to practical problems are described.

One of the important objectives of a course in physical chemistry is to learn how to solve numerical problems. The problems in physical chemistry help emphasize features in the underlying theory, and they illustrate practical applications.

One of the significant changes in the fourth edition is increased emphasis on the thermodynamics and kinetics of biochemical reactions, including the denaturation of proteins and nucleic acids. In this edition there is more discussion of the uses of statistical mechanics, nuclear magnetic relaxation, nano science, and oscillating chemical reactions.

This edition has 32 new problems that can be solved with a hand-held calculator and 35 new problems that require a computer with a mathematical application. There are 34 new figures and eight new tables.

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